Polyether adducts of d-block metal compounds as starting materials for new cluster compounds

摘要

New crystalline cobalt, nickel, zinc, and mercury halide adducts with polyethers as ligands have been isolated, characterized, and identified as [Co(μ-Cl)₂CoCl₂(glyme)₂] (glyme = 1,2-dimethoxyethane), -[CoI₂(H₂O)₂(glyme)₂]²⁺[CoI₄]²⁻, [NiI₂(glyme)₂], [ZnI₂(glyme)], [HgCl₂(glyme)], [CoI₂(diglyme)] (diglyme = bis(2-methoxyethyl)ether), [ZnI₂(diglyme)], [HgI₂(diglyme)], [CoCl(μ-Cl)(diglyme)]₂, [NiI(μ-I)(diglyme)]₂, [Co(μ-Cl)(triglyme)]₂²⁺[CoCl₂(μ-Cl)]₂²⁻, and -[(NiI₂)(triglyme)]. These compounds were obtained from the metal halide salts in solution of glyme or diglyme, and some of them show unusual coordination numbers and arrangements